Glossary entry (derived from question below)
English term or phrase:
the ester configuration flip
French translation:
l'inversion de configuration de l'ester
Added to glossary by
liz askew
Oct 17 09:02
27 days ago
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English term
the ester configuration flip
English to French
Tech/Engineering
Biology (-tech,-chem,micro-)
Brevet pharma
Step3, under strong base conditions, carrying out the ester configuration flip of the (2R,3S)-3-amino-bicyclo[2.2.2]octane-2-carboxylate to give the (2S,3S)-3-amino-bicyclo[2.2.2]octane-2-carboxylate, the strong base comprises at least one selected from the group consisting of sodium tert-butoxide, sodium tert-amylate, lithium diisopropylamide, lithium bis(trimethylsilyl)amide, sodium bis(trimethylsilyl)amide and potassium bis(trimethylsilyl)amide
Proposed translations
(French)
2 +1 | l'inversion de configuration de l'ester | liz askew |
3 | Changement de configuration (stéréochimique) de l'ester | UberTranslate |
Change log
Oct 22, 2024 12:48: liz askew Created KOG entry
Proposed translations
+1
2 hrs
Selected
l'inversion de configuration de l'ester
La stéréoisomérie - TS - Cours Physique-Chimie
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Pour les différencier, il faut identifier, dans les deux molécules, les atomes de carbone qui ont subi une inversion de configuration. Si, d'une molécule à l' ...
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Note added at 2 godz. (2024-10-17 11:28:42 GMT)
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https://www.google.co.uk/search?as_q=inversion de configurat...
Kartable
https://www.kartable.fr › cours › l...
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Translate this page
Pour les différencier, il faut identifier, dans les deux molécules, les atomes de carbone qui ont subi une inversion de configuration. Si, d'une molécule à l' ...
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Note added at 2 godz. (2024-10-17 11:28:42 GMT)
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https://www.google.co.uk/search?as_q=inversion de configurat...
4 KudoZ points awarded for this answer.
Comment: "Merci à tous"
15 mins
Changement de configuration (stéréochimique) de l'ester
Changement de configuration (stéréochimique) de l'ester
Reference comments
2 hrs
Reference:
see
https://en.wikipedia.org/wiki/Ring_flip
In organic chemistry, a ring flip (also known as a ring inversion or ring reversal) is the interconversion of cyclic conformers that have equivalent ring shapes (e.g., from a chair conformer to another chair conformer) that results in the exchange of nonequivalent substituent positions.[1] The overall process generally takes place over several steps, involving coupled rotations about several of the molecule's single bonds, in conjunction with minor deformations of bond angles. Most commonly, the term is used to refer to the interconversion of the two chair conformers of cyclohexane derivatives, which is specifically referred to as a chair flip, although other cycloalkanes and inorganic rings undergo similar processes.
Chair flipAs stated above, a chair flip is a ring inversion specifically of cyclohexane (and its derivatives) from one chair conformer to another, often to reduce steric strain. The term, "flip" is misleading, because the direction of each carbon remains the same; what changes is the orientation. A conformation is a unique structural arrangement of atoms, in particular one achieved through the rotation of single bonds.[2] A conformer is a conformational isomer, a blend of the two words.
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Note added at 2 godz. (2024-10-17 11:24:57 GMT)
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Conformation cyclohexane
Wikipédia
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L'interconversion des conformères de type chaise est appelée inversion de cycle ( ring flipping) ou inversion de chaise (chair-flipping) . Les liaisons ...
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Note added at 2 godz. (2024-10-17 11:26:31 GMT)
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inversion de configuration??
https://cdnsciencepub.com/doi/10.1139/v99-152
In organic chemistry, a ring flip (also known as a ring inversion or ring reversal) is the interconversion of cyclic conformers that have equivalent ring shapes (e.g., from a chair conformer to another chair conformer) that results in the exchange of nonequivalent substituent positions.[1] The overall process generally takes place over several steps, involving coupled rotations about several of the molecule's single bonds, in conjunction with minor deformations of bond angles. Most commonly, the term is used to refer to the interconversion of the two chair conformers of cyclohexane derivatives, which is specifically referred to as a chair flip, although other cycloalkanes and inorganic rings undergo similar processes.
Chair flipAs stated above, a chair flip is a ring inversion specifically of cyclohexane (and its derivatives) from one chair conformer to another, often to reduce steric strain. The term, "flip" is misleading, because the direction of each carbon remains the same; what changes is the orientation. A conformation is a unique structural arrangement of atoms, in particular one achieved through the rotation of single bonds.[2] A conformer is a conformational isomer, a blend of the two words.
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Note added at 2 godz. (2024-10-17 11:24:57 GMT)
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Conformation cyclohexane
Wikipédia
https://fr.wikipedia.org › wiki › C...
·
Translate this page
L'interconversion des conformères de type chaise est appelée inversion de cycle ( ring flipping) ou inversion de chaise (chair-flipping) . Les liaisons ...
--------------------------------------------------
Note added at 2 godz. (2024-10-17 11:26:31 GMT)
--------------------------------------------------
inversion de configuration??
https://cdnsciencepub.com/doi/10.1139/v99-152
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